Proof.
This proof is very similar to the proof of Discriminants, Proposition 49.13.2 and we suggest the reader look at that proof first. We fix $p \geq 0$ throughout the proof.
Let us reformulate the statement. Consider the category $\mathcal{C}$ whose objects, denoted $Y/X$, are locally quasi-finite syntomic morphism $f : Y \to X$ of schemes and whose morphisms $b/a : Y'/X' \to Y/X$ are commutative diagrams
\[ \xymatrix{ Y' \ar[d]_{f'} \ar[r]_ b & Y \ar[d]^ f \\ X' \ar[r]^ a & X } \]
which induce an isomorphism of $Y'$ with an open subscheme of $X' \times _ X Y$. The lemma means that for every object $Y/X$ of $\mathcal{C}$ we have maps $c^ p_{Y/X}$ with property (1) and for every morphism $b/a : Y'/X' \to Y/X$ of $\mathcal{C}$ we have $b^*c^ p_{Y/X} = c^ p_{Y'/X'}$ via the identifications $b^*\det (\mathop{N\! L}\nolimits _{Y/X}) = \det (\mathop{N\! L}\nolimits _{Y'/X'})$ (Discriminants, Section 49.13) and $b^*\Omega ^ p_{Y/X} = \Omega ^ p_{Y'/X'}$ (Lemma 50.2.1).
Given $Y/X$ in $\mathcal{C}$ and $y \in Y$ we can find an affine open $V \subset Y$ and $U \subset X$ with $f(V) \subset U$ such that there exists some maps
\[ \Omega ^ p_{Y/\mathbf{Z}}|_ V \longrightarrow \left( f^*\Omega ^ p_{X/\mathbf{Z}} \otimes _{\mathcal{O}_ Y} \det (\mathop{N\! L}\nolimits _{Y/X}) \right)|_ V \]
with property (1). This follows from picking affine opens as in Discriminants, Lemma 49.10.1 part (5) and Remark 50.18.2. If $\Omega ^ p_{X/\mathbf{Z}}$ is finite locally free and annihilator of the section $\delta (\mathop{N\! L}\nolimits _{Y/X})$ is zero, then these local maps are unique and automatically glue!
Let $\mathcal{C}_{nice} \subset \mathcal{C}$ denote the full subcategory of $Y/X$ such that
$X$ is of finite type over $\mathbf{Z}$,
$\Omega _{X/\mathbf{Z}}$ is locally free, and
the annihilator of $\delta (\mathop{N\! L}\nolimits _{Y/X})$ is zero.
By the remarks in the previous paragraph, we see that for any object $Y/X$ of $\mathcal{C}_{nice}$ we have a unique map $c^ p_{Y/X}$ satisfying condition (1). If $b/a : Y'/X' \to Y/X$ is a morphism of $\mathcal{C}_{nice}$, then $b^*c^ p_{Y/X}$ is equal to $c^ p_{Y'/X'}$ because $b^*\delta (\mathop{N\! L}\nolimits _{Y/X}) = \delta (\mathop{N\! L}\nolimits _{Y'/X'})$ (see Discriminants, Section 49.13). In other words, we have solved the problem on the full subcategory $\mathcal{C}_{nice}$. For $Y/X$ in $\mathcal{C}_{nice}$ we continue to denote $c^ p_{Y/X}$ the solution we've just found.
Consider morphisms
\[ Y_1/X_1 \xleftarrow {b_1/a_1} Y/X \xrightarrow {b_2/a_2} Y_2/X_2 \]
in $\mathcal{C}$ such that $Y_1/X_1$ and $Y_2/X_2$ are objects of $\mathcal{C}_{nice}$. Claim. $b_1^*c^ p_{Y_1/X_1} = b_2^*c^ p_{Y_2/X_2}$. We will first show that the claim implies the lemma and then we will prove the claim.
Let $d, n \geq 1$ and consider the locally quasi-finite syntomic morphism $Y_{n, d} \to X_{n, d}$ constructed in Discriminants, Example 49.10.5. Then $Y_{n, d}$ and $Y_{n, d}$ are irreducible schemes of finite type and smooth over $\mathbf{Z}$. Namely, $X_{n, d}$ is a spectrum of a polynomial ring over $\mathbf{Z}$ and $Y_{n, d}$ is an open subscheme of such. The morphism $Y_{n, d} \to X_{n, d}$ is locally quasi-finite syntomic and étale over a dense open, see Discriminants, Lemma 49.10.6. Thus $\delta (\mathop{N\! L}\nolimits _{Y_{n, d}/X_{n, d}})$ is nonzero: for example we have the local description of $\delta (\mathop{N\! L}\nolimits _{Y/X})$ in Discriminants, Remark 49.13.1 and we have the local description of étale morphisms in Morphisms, Lemma 29.36.15 part (8). Now a nonzero section of an invertible module over an irreducible regular scheme has vanishing annihilator. Thus $Y_{n, d}/X_{n, d}$ is an object of $\mathcal{C}_{nice}$.
Let $Y/X$ be an arbitrary object of $\mathcal{C}$. Let $y \in Y$. By Discriminants, Lemma 49.10.7 we can find $n, d \geq 1$ and morphisms
\[ Y/X \leftarrow V/U \xrightarrow {b/a} Y_{n, d}/X_{n, d} \]
of $\mathcal{C}$ such that $V \subset Y$ and $U \subset X$ are open. Thus we can pullback the canonical morphism $c^ p_{Y_{n, d}/X_{n, d}}$ constructed above by $b$ to $V$. The claim guarantees these local isomorphisms glue! Thus we get a well defined global maps $c^ p_{Y/X}$ with property (1). If $b/a : Y'/X' \to Y/X$ is a morphism of $\mathcal{C}$, then the claim also implies that the similarly constructed map $c^ p_{Y'/X'}$ is the pullback by $b$ of the locally constructed map $c^ p_{Y/X}$. Thus it remains to prove the claim.
In the rest of the proof we prove the claim. We may pick a point $y \in Y$ and prove the maps agree in an open neighbourhood of $y$. Thus we may replace $Y_1$, $Y_2$ by open neighbourhoods of the image of $y$ in $Y_1$ and $Y_2$. Thus we may assume $Y, X, Y_1, X_1, Y_2, X_2$ are affine. We may write $X = \mathop{\mathrm{lim}}\nolimits X_\lambda $ as a cofiltered limit of affine schemes of finite type over $X_1 \times X_2$. For each $\lambda $ we get
\[ Y_1 \times _{X_1} X_\lambda \quad \text{and}\quad X_\lambda \times _{X_2} Y_2 \]
If we take limits we obtain
\[ \mathop{\mathrm{lim}}\nolimits Y_1 \times _{X_1} X_\lambda = Y_1 \times _{X_1} X \supset Y \subset X \times _{X_2} Y_2 = \mathop{\mathrm{lim}}\nolimits X_\lambda \times _{X_2} Y_2 \]
By Limits, Lemma 32.4.11 we can find a $\lambda $ and opens $V_{1, \lambda } \subset Y_1 \times _{X_1} X_\lambda $ and $V_{2, \lambda } \subset X_\lambda \times _{X_2} Y_2$ whose base change to $X$ recovers $Y$ (on both sides). After increasing $\lambda $ we may assume there is an isomorphism $V_{1, \lambda } \to V_{2, \lambda }$ whose base change to $X$ is the identity on $Y$, see Limits, Lemma 32.10.1. Then we have the commutative diagram
\[ \xymatrix{ & Y/X \ar[d] \ar[ld]_{b_1/a_1} \ar[rd]^{b_2/a_2} \\ Y_1/X_1 & V_{1, \lambda }/X_\lambda \ar[l] \ar[r] & Y_2/X_2 } \]
Thus it suffices to prove the claim for the lower row of the diagram and we reduce to the case discussed in the next paragraph.
Assume $Y, X, Y_1, X_1, Y_2, X_2$ are affine of finite type over $\mathbf{Z}$. Write $X = \mathop{\mathrm{Spec}}(A)$, $X_ i = \mathop{\mathrm{Spec}}(A_ i)$. The ring map $A_1 \to A$ corresponding to $X \to X_1$ is of finite type and hence we may choose a surjection $A_1[x_1, \ldots , x_ n] \to A$. Similarly, we may choose a surjection $A_2[y_1, \ldots , y_ m] \to A$. Set $X'_1 = \mathop{\mathrm{Spec}}(A_1[x_1, \ldots , x_ n])$ and $X'_2 = \mathop{\mathrm{Spec}}(A_2[y_1, \ldots , y_ m])$. Observe that $\Omega _{X'_1/\mathbf{Z}}$ is the direct sum of the pullback of $\Omega _{X_1/\mathbf{Z}}$ and a finite free module. Similarly for $X'_2$. Set $Y'_1 = Y_1 \times _{X_1} X'_1$ and $Y'_2 = Y_2 \times _{X_2} X'_2$. We get the following diagram
\[ Y_1/X_1 \leftarrow Y'_1/X'_1 \leftarrow Y/X \rightarrow Y'_2/X'_2 \rightarrow Y_2/X_2 \]
Since $X'_1 \to X_1$ and $X'_2 \to X_2$ are flat, the same is true for $Y'_1 \to Y_1$ and $Y'_2 \to Y_2$. It follows easily that the annihilators of $\delta (\mathop{N\! L}\nolimits _{Y'_1/X'_1})$ and $\delta (\mathop{N\! L}\nolimits _{Y'_2/X'_2})$ are zero. Hence $Y'_1/X'_1$ and $Y'_2/X'_2$ are in $\mathcal{C}_{nice}$. Thus the outer morphisms in the displayed diagram are morphisms of $\mathcal{C}_{nice}$ for which we know the desired compatibilities. Thus it suffices to prove the claim for $Y'_1/X'_1 \leftarrow Y/X \rightarrow Y'_2/X'_2$. This reduces us to the case discussed in the next paragraph.
Assume $Y, X, Y_1, X_1, Y_2, X_2$ are affine of finite type over $\mathbf{Z}$ and $X \to X_1$ and $X \to X_2$ are closed immersions. Consider the open embeddings $Y_1 \times _{X_1} X \supset Y \subset X \times _{X_2} Y_2$. There is an open neighbourhood $V \subset Y$ of $y$ which is a standard open of both $Y_1 \times _{X_1} X$ and $X \times _{X_2} Y_2$. This follows from Schemes, Lemma 26.11.5 applied to the scheme obtained by glueing $Y_1 \times _{X_1} X$ and $X \times _{X_2} Y_2$ along $Y$; details omitted. Since $X \times _{X_2} Y_2$ is a closed subscheme of $Y_2$ we can find a standard open $V_2 \subset Y_2$ such that $V_2 \times _{X_2} X = V$. Similarly, we can find a standard open $V_1 \subset Y_1$ such that $V_1 \times _{X_1} X = V$. After replacing $Y, Y_1, Y_2$ by $V, V_1, V_2$ we reduce to the case discussed in the next paragraph.
Assume $Y, X, Y_1, X_1, Y_2, X_2$ are affine of finite type over $\mathbf{Z}$ and $X \to X_1$ and $X \to X_2$ are closed immersions and $Y_1 \times _{X_1} X = Y = X \times _{X_2} Y_2$. Write $X = \mathop{\mathrm{Spec}}(A)$, $X_ i = \mathop{\mathrm{Spec}}(A_ i)$, $Y = \mathop{\mathrm{Spec}}(B)$, $Y_ i = \mathop{\mathrm{Spec}}(B_ i)$. Then we can consider the affine schemes
\[ X' = \mathop{\mathrm{Spec}}(A_1 \times _ A A_2) = \mathop{\mathrm{Spec}}(A') \quad \text{and}\quad Y' = \mathop{\mathrm{Spec}}(B_1 \times _ B B_2) = \mathop{\mathrm{Spec}}(B') \]
Observe that $X' = X_1 \amalg _ X X_2$ and $Y' = Y_1 \amalg _ Y Y_2$, see More on Morphisms, Lemma 37.14.1. By More on Algebra, Lemma 15.5.1 the rings $A'$ and $B'$ are of finite type over $\mathbf{Z}$. By More on Algebra, Lemma 15.6.4 we have $B' \otimes _ A A_1 = B_1$ and $B' \times _ A A_2 = B_2$. In particular a fibre of $Y' \to X'$ over a point of $X' = X_1 \amalg _ X X_2$ is always equal to either a fibre of $Y_1 \to X_1$ or a fibre of $Y_2 \to X_2$. By More on Algebra, Lemma 15.6.8 the ring map $A' \to B'$ is flat. Thus by Discriminants, Lemma 49.10.1 part (3) we conclude that $Y'/X'$ is an object of $\mathcal{C}$. Consider now the commutative diagram
\[ \xymatrix{ & Y/X \ar[ld]_{b_1/a_1} \ar[rd]^{b_2/a_2} \\ Y_1/X_1 \ar[rd] & & Y_2/X_2 \ar[ld] \\ & Y'/X' } \]
Now we would be done if $Y'/X'$ is an object of $\mathcal{C}_{nice}$, but this is almost never the case. Namely, then pulling back $c^ p_{Y'/X'}$ around the two sides of the square, we would obtain the desired conclusion. To get around the problem that $Y'/X'$ is not in $\mathcal{C}_{nice}$ we note the arguments above show that, after possibly shrinking all of the schemes $X, Y, X_1, Y_1, X_2, Y_2, X', Y'$ we can find some $n, d \geq 1$, and extend the diagram like so:
\[ \xymatrix{ & Y/X \ar[ld]_{b_1/a_1} \ar[rd]^{b_2/a_2} \\ Y_1/X_1 \ar[rd] & & Y_2/X_2 \ar[ld] \\ & Y'/X' \ar[d] \\ & Y_{n, d}/X_{n, d} } \]
and then we can use the already given argument by pulling back from $c^ p_{Y_{n, d}/X_{n, d}}$. This finishes the proof.
$\square$
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